ASTM A320 – Mechanical, Material & Chemical Properties

The ASTM A320 specification establishes the essential mechanical and chemical requirements for alloy and stainless steel bolting used in low-temperature applications. Centered on high-strength ferritic grades (quenched and tempered) and corrosion-resistant austenitic grades (solution annealed or strain-hardened), the standard ensures reliability for pressure-retaining components. Key technical focuses include stringent tensile property minimums and mandatory Charpy impact energy absorption levels—ranging from 20 to 40 ft-lbf—to prevent brittle failure in sub-zero service conditions.

Mechanical Properties

The mechanical requirements for ASTM A320 bolting are determined by the alloy's heat-treated condition and diameter. Ferritic grades, intended for high-strength low-temperature service, must meet stringent tensile and yield minimums through quenching and tempering. Austenitic grades offer a range of properties based on their class: Class 1 and 1A provide standard solution-treated properties, while Class 2 leverages strain hardening to achieve significantly higher strength, particularly in smaller thread sizes. Compliance is verified through tensile testing and hardness measurements—such as Brinell (HBW) or Rockwell (HRC/HRB)—to ensure structural reliability.

Mechanical Requirements
Grade Thread Size (inch & metric) Tensile Strength, min (ksi) Yield Strength 0.2% offset, min (ksi) Elongation in 2 in. or 50 mm, min (%) Reduction of Area, min (%) Hardness, max
L7, L7A, L7B, L7C, L70, L71, L72, L73 2-1/2" or M65 and under 125 105 16 50 321 HBW or 35 HRC
L43 4" or M100 and under 125 105 16 50 321 HBW or 35 HRC
L7M 2-1/2" or M65 and under 100 80 18 50 235 HBW or 99 HRB
L1 1" or M25 and under 125 105 16 50 -
B8, B8C, B8M, B8P, B8F, B8T, B8LN, B8MLN (Class 1) All Diameters 75 30 30 50 223 HBW or 96 HRB
B8A, B8CA, B8MA, B8PA, B8FA, B8TA, B8LNA, B8MLNA (Class 1A) All Diameters 75 30 30 50 192 HBW or 90 HRB
B8, B8C, B8P, B8F, B8T (Class 2) 3/4" or M20 and under 125 100 12 35 321 HBW or 35 HRC
over 3/4" to 1" or M20 to M25 115 80 15 30 321 HBW or 35 HRC
over 1" to 1-1/4" or M25 to M32 105 65 20 35 321 HBW or 35 HRC
over 1-1/4" to 1-1/2" or M32 to M40 100 50 28 45 321 HBW or 35 HRC
B8M (Class 2) 3/4" or M20 and under 110 95 15 45 321 HBW or 35 HRC
over 3/4" to 1" or M20 to M25 100 80 20 45 321 HBW or 35 HRC
over 1" to 1-1/4" or M25 to M32 95 65 25 45 321 HBW or 35 HRC
over 1-1/4" to 1-1/2" or M32 to M40 90 50 30 45 321 HBW or 35 HRC

Material Properties

The ASTM A320 specification defines stringent chemical composition requirements across various ferritic and austenitic steel grades to guarantee reliable performance in low-temperature service. Ferritic grades, such as L7 and L43, are alloyed with chromium and molybdenum for hardenability, while austenitic grades like B8 and B8M rely on high nickel and chromium concentrations for cryogenic stability. Specialized chemical controls are also mandated, such as the addition of boron in Grade L1 or selenium for free-machining in Grade B8F, to meet specific mechanical or manufacturing objectives.

Chemical Requirements (Composition, %)
Grade UNS Designation Carbon, (%) Manganese, (%) Phosphorus, (%) Sulfur, (%) Silicon, (%) Chromium, (%) Nickel, (%) Molybdenum, (%) Vanadium, (%) Aluminum, (%) Columbium + Tantalum, (%) Titanium, (%) Nitrogen, (%) Boron/Selenium, (%)
L7, L7M, L70 - 0.38 - 0.48 0.75 - 1.00 0.035 (max) 0.040 (max) 0.15 - 0.35 0.80 - 1.10 - 0.15 - 0.25 - - - - - -
L7A, L71 - 0.35 - 0.40 0.70 - 0.90 0.035 (max) 0.040 (max) 0.15 - 0.35 - - 0.20 - 0.30 - - - - - -
L7B, L72 - 0.35 - 0.40 0.60 - 0.90 0.035 (max) 0.040 (max) 0.15 - 0.35 0.70 - 0.90 - 0.15 - 0.25 - - - - - -
L7C, L73 - 0.38 - 0.43 0.70 - 0.90 0.035 (max) 0.040 (max) 0.15 - 0.35 0.40 - 0.60 1.65 - 2.00 0.20 - 0.30 - - - - - -
L43 - 0.38 - 0.43 0.60 - 0.85 0.035 (max) 0.040 (max) 0.15 - 0.35 0.70 - 0.90 1.65 - 2.00 0.20 - 0.30 - - - - - -
L1 - 0.17 - 0.24 0.70 - 1.40 0.035 (max) 0.050 (max) 0.15 - 0.30 - - - - - - - - 0.001 - 0.003 (Boron)
B8, B8A S30400 (304) 0.08 (max) 2.00 (max) 0.045 (max) 0.030 (max) 1.00 (max) 18.0 - 20.0 8.0 - 11.0 - - - - - - -
B8C, B8CA S34700 (347) 0.08 (max) 2.00 (max) 0.045 (max) 0.030 (max) 1.00 (max) 17.0 - 19.0 9.0 - 12.0 - - - 10 x Carbon content (min) - 1.10 (max) - - -
B8T, B8TA S32100 (321) 0.08 (max) 2.00 (max) 0.045 (max) 0.030 (max) 1.00 (max) 17.0 - 19.0 9.0 - 12.0 - - - - 5 x Carbon content (min) - -
B8P, B8PA S30500 0.08 (max) 2.00 (max) 0.045 (max) 0.030 (max) 1.00 (max) 17.0 - 19.0 10.5 - 13.0 - - - - - - -
B8F, B8FA S30300 (303) / S30323 (303Se) 0.15 (max) 2.00 (max) 0.20 (max) 0.15 (min) or 0.06 (max) 1.00 (max) 17.0 - 19.0 8.0 - 10.0 0.60 (max) - - - - - 0.35 (min) Selenium (if S30323)
B8M, B8MA S31600 (316) 0.08 (max) 2.00 (max) 0.045 (max) 0.030 (max) 1.00 (max) 16.0 - 18.0 10.0 - 14.0 2.00 - 3.00 - - - - - -
B8LN, B8LNA S30453 0.030 (max) 2.00 (max) 0.045 (max) 0.030 (max) 1.00 (max) 18.0 - 20.0 8.0 - 10.5 - - - - - 0.10 - 0.16 -
B8MLN, B8MLNA S31653 0.030 (max) 2.00 (max) 0.045 (max) 0.030 (max) 1.00 (max) 16.0 - 18.0 10.0 - 14.0 2.00 - 3.00 - - - - 0.10 - 0.16 -