ASTM F468 – Mechanical & Material Property
The ASTM F468 specification establishes the chemical, mechanical, and dimensional requirements for commercial wrought nonferrous fasteners intended for general service applications. This standard is a critical reference for engineers and procurement professionals selecting fasteners that require specific properties like corrosion resistance, high strength-to-weight ratios, or non-magnetic characteristics. This specification covers three primary fastener types: bolts, hex cap screws, and studs with nominal diameters ranging from 0.250 to 1.500 in. inclusive. It categorizes materials into four major alloy groups:
- Copper and Copper-Base Alloys: Including ETP copper (110), various brasses, naval brass, and silicon/aluminum bronzes.
- Nickel and Nickel-Base Alloys: Including Ni-Cu (400/405), Ni-Cu-Al (500), and high-performance Ni-Cr-Mo alloys like 625 and 276.
- Aluminum-Base Alloys: Specifically 2024-T4, 6061-T6, and 7075-T73 tempers.
- Titanium and Titanium-Base Alloys: Ranging from commercially pure Grades 1, 2, and 4 to high-strength alloys like Ti-6Al-4V (Grade 5).
For complementary components, nuts used with these fasteners are covered under the ASTM F467 specification. To correctly apply this specification to your project or procurement, the following technical requirements must be observed:
Fasteners may be cold formed, hot formed, or machined at the manufacturer's option unless a specific process is requested. The final condition is alloy-dependent:
- Copper and Nickel 400/405: Typically furnished as formed or stress relieved at the manufacturer's option.
- Nickel 500: Must be solution annealed and aged.
- Aluminum Alloys: Must be solution treated and aged (naturally, artificially, or stabilized depending on the alloy).
Mechanical Properties
The mechanical property requirements for fasteners under the ASTM F468 specification are determined by the specific alloy, the length of the product, and its nominal diameter. These properties are essential for ensuring that nonferrous bolts, screws, and studs can withstand the intended service loads without failure.
To verify compliance, the specification defines two primary testing methods: Full-Size Testing is preferred for fasteners with a breaking load of 120,000 lbf or less to measure actual tensile and yield strength, while Machined Specimen Testing is used for fasteners exceeding that load or where full-size testing is impractical. In any instance where both tension and hardness tests are conducted, the tension test results take precedence for final Acceptance Priority.
The mechanical integrity of these fasteners is governed by several critical factors: Yield Strength Calculation for full-size products uses the specific Tensile Stress Area (As) for the product diameter and thread pitch, with the yield point defined at an offset of 0.2% gage length. Ductility is measured as "Elongation in 4D," using a gage length equivalent to four times the diameter of the test specimen.
For alloys other than aluminum and titanium, fasteners too short for tension testing must conform to specific Hardness Requirements. For aluminum alloys, when tension testing is not feasible, a shear test must be performed, requiring minimum strengths such as 37 ksi for 2024-T4 or 41 ksi for 7075-T73.
| Mechanical Properties Requirements | |||||||
|---|---|---|---|---|---|---|---|
| Alloy | Mechanical Property Marking | Nominal Thread Diameter, in. | Full-Size Tests | Machined Specimen Tests | |||
| Tensile Strength, min, ksi | Yield Strength, min, ksi | Tensile Strength, min, ksi | Yield Strength, min, ksi | Elongation in 4D, min, % | |||
| Copper and Copper-Base Alloys | |||||||
| Cu 110 | F 468A | all | 30 | 10 | 30 | 10 | 15 |
| Cu 260 | F 468AB | all | 55 | 50 | 55 | 50 | 35 |
| Cu 270 | F 468B | all | 55 | 50 | 55 | 50 | 35 |
| Cu 462 | F 468C | all | 50 | 25 | 50 | 25 | 20 |
| Cu 464 | F 468D | all | 50 | 15 | 50 | 15 | 25 |
| Cu 510 | F 468E | all | 60 | 35 | 55 | 30 | 15 |
| Cu 613 | F 468F | 1/4 to 1/2 | 80 | 50 | 80 | 50 | 30 |
| Cu 613 | F 468F | 5/8 to 1-1/2 | 75 | 45 | 75 | 45 | 30 |
| Cu 614 | F 468G | all | 75 | 35 | 75 | 35 | 30 |
| Cu 630 | F 468H | all | 100 | 50 | 100 | 50 | 5 |
| Cu 642 | F 468J | all | 75 | 35 | 75 | 35 | 10 |
| Cu 651 | F 468K | 1/4 to 3/4 | 70 | 55 | 70 | 53 | 8 |
| Cu 651 | F 468K | 7/8 to 1-1/2 | 54 | 40 | 54 | 38 | 8 |
| Cu 655 | F 468L | all | 50 | 20 | 50 | 15 | 20 |
| Cu 661 | F 468M | all | 70 | 35 | 70 | 35 | 15 |
| Cu 675 | F 468N | all | 55 | 25 | 55 | 25 | 20 |
| Cu 710 | F 468P | all | 45 | 15 | 45 | 15 | 40 |
| Cu 715 | F 468R | all | 55 | 20 | 55 | 20 | 45 |
| Nickel and Nickel-Base Alloys | |||||||
| Ni 59 Grade 1 | F468FN | all | 120 | 85 | 120 | 85 | 20 |
| Ni 59 Grade 2 | F468GN | all | 135 | 125 | 135 | 125 | 20 |
| Ni 59 Grade 3 | F468HN | all | 160 | 150 | 160 | 150 | 20 |
| Ni 59 Grade 4 | F468JN | all | 100 | 45 | 100 | 45 | 25 |
| Ni 335 | F 468S | all | 115 | 45 | 115 | 45 | 35 |
| Ni 276 | F 468T | all | 110 | 45 | 110 | 45 | 25 |
| Ni 400 | F 468U | 1/4 to 3/4 | 80 | 40 | 80 | 40 | 20 |
| Ni 400 | F 468U | 7/8 to 1-1/2 | 70 | 30 | 70 | 30 | 20 |
| Ni 400 HF | F 468HF | all | 70 | 30 | 70 | 30 | 20 |
| Ni 405 | F 468V | all | 70 | 30 | 70 | 30 | 20 |
| Ni 500 | F 468W | 1/4 to 7/8 | 130 | 90 | 130 | 90 | 20 |
| Ni 500 | F 468W | 1 to 1-1/2 | 130 | 85 | 130 | 85 | 20 |
| Ni 625 | F 468AC | all | 120 | 60 | 120 | 60 | 30 |
| Ni 686 Grade 1 | F468BN | all | 120 | 85 | 120 | 85 | 20 |
| Ni 686 Grade 2 | F468CN | all | 135 | 125 | 135 | 125 | 20 |
| Ni 686 Grade 3 | F468DN | all | 160 | 150 | 160 | 150 | 20 |
| Ni 686 Grade 4 | F468EN | all | 100 | 45 | 100 | 45 | 25 |
| Aluminum-Base Alloys | |||||||
| Al 2024-T4 | F 468X | all | 62 | 36 | 62 | 40 | 10 |
| Al 6061-T6 | F 468Y | all | 42 | 31 | 42 | 35 | 10 |
| Al 7075-T73 | F 468Z | all | 68 | 50 | 68 | 56 | 10 |
| Titanium and Titanium-Base Alloys | |||||||
| Ti 1 | F 468AT | all | 35 | 30 | 35 | 25 | 24 |
| Ti 2 | F 468BT | all | 50 | 45 | 50 | 40 | 20 |
| Ti 4 | F 468CT | all | 80 | 75 | 80 | 70 | 15 |
| Ti 5 Class A | F 468DT | all | 130 | 125 | 130 | 120 | 10 |
| Ti 5 Class B | F 468HT | all | 130 | 125 | 130 | 120 | 10 |
| Ti 7 | F 468ET | all | 50 | 45 | 50 | 40 | 20 |
| Ti 19 | F 468FT | all | 120 | 115 | 120 | 115 | 15 |
| Ti 23 | F 468GT | all | 120 | 110 | 120 | 110 | 10 |
| Ti-5-1-1-1 | F 468HT | all | 100 | 90 | 100 | 85 | 10 |
| Tensile Stress Areas and Threads per Inch | ||||||
|---|---|---|---|---|---|---|
| Nominal Size, in. | Coarse Threads—UNC | Fine Threads—UNF | 8 Thread Series—8UN | |||
| Threads/in. | Stress Area, in.² | Threads/in. | Stress Area, in.² | Threads/in. | Stress Area, in.² | |
| 1/4 | 20 | 0.0318 | 28 | 0.0364 | — | — |
| 5/16 | 18 | 0.0524 | 24 | 0.0580 | — | — |
| 3/8 | 16 | 0.0775 | 24 | 0.0878 | — | — |
| 7/16 | 14 | 0.1063 | 20 | 0.1187 | — | — |
| 1/2 | 13 | 0.1419 | 20 | 0.1599 | — | — |
| 9/16 | 12 | 0.1820 | 18 | 0.2030 | — | — |
| 5/8 | 11 | 0.2260 | 18 | 0.2560 | — | — |
| 3/4 | 10 | 0.3340 | 16 | 0.3730 | — | — |
| 7/8 | 9 | 0.4620 | 14 | 0.5090 | — | — |
| 1 | 8 | 0.6060 | 12 | 0.6630 | — | — |
| 1-1/8 | 7 | 0.7630 | 12 | 0.8560 | 8 | 0.790 |
| 1-1/4 | 7 | 0.9690 | 12 | 1.0730 | 8 | 1.000 |
| 1-3/8 | 6 | 1.1550 | 12 | 1.3150 | 8 | 1.233 |
| 1-1/2 | 6 | 1.4050 | 12 | 1.5810 | 8 | 1.492 |
Material Properties
The material and chemical properties of fasteners under the ASTM F468 specification are strictly defined to ensure consistency and performance across a wide range of nonferrous alloys. These requirements govern the elemental makeup of the finished products, providing the foundation for their unique mechanical and corrosion-resistant characteristics.
To maintain high quality standards, the specification mandates several layers of chemical verification:
- Strict Elemental Limits: Fasteners must conform to the specific chemical requirements detailed in Table 1 for their designated alloy.
- Balance Elements: For many alloys, the primary element (e.g., Copper, Aluminum, or Titanium) is calculated arithmetically as the "balance" by subtracting the total of all other named elements from 100%.
- Verification Methods: Manufacturers may perform analysis on randomly selected finished fasteners or report the analysis of the raw material, provided that heat and lot identities have been strictly maintained.
- Residual Elements: Elements present in small quantities inherent to the manufacturing process but not intentionally added are considered residuals. These typically do not need to be reported unless explicitly required by the purchaser.
Different alloy groups have specific requirements that must be followed for full compliance:
- Nickel Alloys: For all nickel-base alloys, cobalt is to be counted as nickel. Additionally, Alloy 625 material must be refined using either electroslag remelting (ESR) or vacuum arc remelting (VAR) processes.
- Aluminum Alloys: For aluminum fasteners, manufacturers have the option to furnish a certificate of conformance instead of detailed test reports to certify compliance with the chemical composition.
- Copper Alloys: Certain silicon bronze alloys, such as C65100, have specific provisions where an alloy containing up to 2.6% silicon is acceptable under certain elemental sum conditions.
| Chemical Composition, (%) | ||||||||||||||||||||||||||||||||
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| Group | UNS Designation Number | Alloy Number | General Name | Aluminum | Arsenic | Carbon | Chromium | Copper | Iron | Manganese | Nickel | Phosphorus | Silicon | Zinc | Lead | Tin | Titanium | Cobalt | Molybdenum | Sulfur | Vanadium | Tungsten | Niobium | Magnesium | Hydrogen | Nitrogen | Oxygen | Palladium | Zirconium | Ruthenium | Residuals (Each) | Residuals (Total) |
| Copper and Copper-Base Alloys | ||||||||||||||||||||||||||||||||
| Copper | C11000 | 110 | ETP copper | - | - | - | - | 99.9 min | - | - | - | - | - | - | - | - | - | - | - | - | - | - | - | - | - | - | - | - | - | - | - | - |
| Copper | C26000 | 260 | brass | - | - | - | - | 68.5–71.5 | 0.05 max | - | - | - | - | balance | 0.07 max | - | - | - | - | - | - | - | - | - | - | - | - | - | - | - | - | - |
| Copper | C27000 | 270 | brass | - | - | - | - | 63.0–68.5 | 0.07 max | - | - | - | - | balance | 0.10 max | - | - | - | - | - | - | - | - | - | - | - | - | - | - | - | - | - |
| Copper | C46200 | 462 | naval brass | - | - | - | - | 62.0–65.0 | 0.10 max | - | - | - | - | balance | 0.20 max | 0.5–1.0 | - | - | - | - | - | - | - | - | - | - | - | - | - | - | - | - |
| Copper | C46400 | 464 | naval brass | - | - | - | - | 59.0–62.0 | 0.10 max | - | - | - | - | balance | 0.20 max | 0.5–1.0 | - | - | - | - | - | - | - | - | - | - | - | - | - | - | - | - |
| Copper | C51000 | 510 | phosphor bronze | - | - | - | - | balance | 0.10 max | - | - | 0.03–0.35 | - | 0.30 max | 0.05 max | 4.2–5.8 | - | - | - | - | - | - | - | - | - | - | - | - | - | - | - | - |
| Copper | C61300 | 613 | aluminum bronze | 6.0–7.5 | - | - | - | balance | 2.0–3.0 | 0.10 max | 0.10 max | 0.015 max | 0.10 max | 0.05 max | 0.01 max | 0.20–0.50 | - | - | - | - | - | - | - | - | - | - | - | - | - | - | - | - |
| Copper | C61400 | 614 | aluminum bronze | 6.0–8.0 | - | - | - | 88.00 min | 1.5–3.5 | 1.0 max | - | - | - | - | - | - | - | - | - | - | - | - | - | - | - | - | - | - | - | - | - | - |
| Copper | C63000 | 630 | aluminum bronze | 9.0–11.0 | - | - | - | 78.00 min | 2.0–4.0 | 1.5 max | 4.0–5.5 | - | 0.25 max | - | - | 0.20 max | - | - | - | - | - | - | - | - | - | - | - | - | - | - | - | - |
| Copper | C64200 | 642 | aluminum silicon bronze | 6.3–7.6 | 0.15 max | - | - | 88.65 min | 0.30 max | 0.10 max | 0.25 max | - | 1.5–2.25 | 0.50 max | 0.05 max | 0.20 max | - | - | - | - | - | - | - | - | - | - | - | - | - | - | - | - |
| Copper | C65100 | 651 | silicon bronze | - | - | - | - | 96.00 min | 0.8 max | 0.7 max | - | - | 0.8–2.0 | 1.5 max | 0.05 max | - | - | - | - | - | - | - | - | - | - | - | - | - | - | - | - | - |
| Copper | C65500 | 655 | silicon bronze | - | - | - | - | 94.80 min | 0.8 max | 1.5 max | 0.6 max | - | 2.8–3.8 | 1.5 max | 0.05 max | - | - | - | - | - | - | - | - | - | - | - | - | - | - | - | - | - |
| Copper | C66100 | 661 | silicon bronze | - | - | - | - | 94.00 min | 0.25 max | 1.5 max | - | - | 2.8–3.5 | 1.5 max | 0.20–0.8 | - | - | - | - | - | - | - | - | - | - | - | - | - | - | - | - | - |
| Copper | C67500 | 675 | manganese bronze | - | - | - | - | 57.0–60.0 | 0.8–2.0 | 0.05–0.5 | - | - | - | balance | 0.20 max | 0.5–1.5 | - | - | - | - | - | - | - | - | - | - | - | - | - | - | - | - |
| Copper | C71000 | 710 | cupro-nickel | - | - | - | - | 74.00 min | 0.60 max | 1.00 max | 19.0–23.00 | - | - | 1.00 max | 0.05 max | - | - | - | - | - | - | - | - | - | - | - | - | - | - | - | - | - |
| Copper | C71500 | 715 | cupro-nickel | - | - | - | - | 65.00 min | 0.40–0.7 | 1.00 max | 29.0–33.0 | - | - | 1.00 max | 0.05 max | - | - | - | - | - | - | - | - | - | - | - | - | - | - | - | - | - |
| Nickel and Nickel-Base Alloys | ||||||||||||||||||||||||||||||||
| Nickel | N10001 | 335 | NiMo | 2.30–3.15 | - | 0.05 max | 1.0 max | - | 4.0–6.0 | 1.0 max | balance | - | 1.00 max | - | - | - | - | 2.50 max | 26.0–30.0 | 0.030 max | 0.2–0.4 | - | - | - | - | - | - | - | - | - | - | - |
| Nickel | N10276 | 276 | Ni-Mo-Cr | - | - | 0.02 max | 14.5–16.5 | - | 4.0–7.0 | 1.00 max | balance | 0.040 max | 0.08 max | - | - | - | - | 2.50 max | 15.0–17.0 | 0.030 max | 0.35 max | 3.0–4.5 | - | - | - | - | - | - | - | - | - | - |
| Nickel | N04400 | 400 | NiCu -Class A | - | - | 0.3 max | - | balance | 2.5 max | 2.0 max | 63.0–70.0 | - | 0.5 max | - | - | - | - | - | - | 0.024 max | - | - | - | - | - | - | - | - | - | - | - | - |
| Nickel | N04405 | 405 | Ni-Cu Class B | - | - | 0.3 max | - | balance | 2.5 max | 2.0 max | 63.0–70.0 | - | 0.5 max | - | - | - | - | - | - | 0.025–0.060 | - | - | - | - | - | - | - | - | - | - | - | - |
| Nickel | N05500 | 500 | NiCu-Al | 2.30–3.15 | - | 0.25 max | - | balance | 2.0 max | 1.5 max | 63.0–70.0 | - | 0.5 max | - | - | - | 0.35–0.85 | - | - | 0.010 max | - | - | - | - | - | - | - | - | - | - | - | - |
| Nickel | N06059 | 59 | NiCr-Mo | 0.1–0.4 | - | 0.010 max | 22.0–24.0 | 0.5 max | 1.5 max | 0.5 max | balance | 0.015 max | 0.10 max | - | - | - | - | - | 15.0–16.5 | 0.010 max | - | - | - | - | - | - | - | - | - | - | - | - |
| Nickel | N06625 | 625 | Ni-Cr-Mo-Cb | 0.40 max | - | 0.10 max | 20.0–23.0 | - | 5.0 max | 0.50 max | 58.0 min | 0.015 max | 0.50 max | - | - | - | 0.40 max | 1.00 max | 8.0–10.0 | 0.015 max | - | - | 3.15–4.15 | - | - | - | - | - | - | - | - | - |
| Nickel | N06686 | 686 | NiCr--MoW- | - | - | 0.010 max | 19.0–23.00 | - | 5.0 max | 0.75 max | balance | 0.04 max | 0.08 max | - | - | - | 0.02–0.25 | - | 15.0–17.0 | 0.02 max | - | 3.0–4.4 | - | - | - | - | - | - | - | - | - | - |
| Aluminum-Base Alloys | ||||||||||||||||||||||||||||||||
| Aluminum | A92024 | 2024 | Aluminum 2024 | balance | - | - | 0.10 max | 3.8–4.9 | 0.50 max | 0.30–0.9 | - | - | 0.50 max | 0.25 max | - | - | 0.15 max | - | - | - | - | - | - | 1.2–1.8 | - | - | - | - | - | - | 0.05 max | 0.15 max |
| Aluminum | A96061 | 6061 | Aluminum 6061 | balance | - | - | 0.04–0.35 | 0.15–0.40 | 0.7 max | 0.15 max | - | - | 0.40–0.8 | 0.25 max | - | - | 0.15 max | - | - | - | - | - | - | 0.8–1.2 | - | - | - | - | - | - | 0.05 max | 0.15 max |
| Aluminum | A97075 | 7075 | Aluminum 7075 | balance | - | - | 0.18–0.35 | 1.2–2.0 | 0.50 max | 0.30 max | - | - | 0.40 max | 5.1–6.1 | - | - | 0.200 max | - | - | - | - | - | - | 2.1–2.9 | - | - | - | - | - | - | 0.05 max | 0.15 max |
| Titanium and Titanium-Base Alloys | ||||||||||||||||||||||||||||||||
| Titanium | R50250 | 1 | Titanium Gr 1 | - | - | 0.10 max | - | - | 0.20 max | - | - | - | - | - | - | - | balance | - | - | - | - | - | - | - | 0.0125 max | 0.05 max | 0.18 max | - | - | - | 0.1 max | 0.4 max |
| Titanium | R50400 | 2 | Titanium Gr 2 | - | - | 0.10 max | - | - | 0.30 max | - | - | - | - | - | - | - | balance | - | - | - | - | - | - | - | 0.0125 max | 0.05 max | 0.25 max | - | - | - | 0.1 max | 0.4 max |
| Titanium | R50700 | 4 | Titanium Gr 4 | - | - | 0.10 max | - | - | 0.50 max | - | - | - | - | - | - | - | balance | - | - | - | - | - | - | - | 0.0125 max | 0.07 max | 0.40 max | - | - | - | 0.1 max | 0.4 max |
| Titanium | R56400 | 5 | Titanium Gr 5 | 5.5–6.75 | - | 0.10 max | - | - | 0.40 max | - | - | - | - | - | - | - | balance | - | - | - | 3.5–4.5 | - | - | - | 0.0125 max | 0.05 max | 0.20 max | - | - | - | 0.1 max | 0.4 max |
| Titanium | R56401 | 23 | Titanium Ti-6Al-4V ELI | 5.5–6.5 | - | 0.08 max | - | - | 0.25 max | - | - | - | - | - | - | - | balance | - | - | - | 3.5–4.5 | - | - | - | 0.0125 max | 0.05 max | 0.13 max | - | - | - | 0.1 max | 0.4 max |
| Titanium | R52400 | 7 | Titanium Gr 7 | - | - | 0.10 max | - | - | 0.30 max | - | - | - | - | - | - | - | balance | - | - | - | - | - | - | - | 0.0125 max | 0.05 max | 0.25 max | 0.12–0.25 | - | - | 0.1 max | 0.4 max |
| Titanium | R58640 | 19 | Titanium Ti-38-6-44 | 3.0–4.0 | - | 0.05 max | 5.5–6.5 | - | 0.30 max | - | - | - | 0.10 max | - | - | - | balance | - | 3.5–4.5 | - | 7.5–8.5 | - | - | - | 0.0200 max | 0.03 max | 0.12 max | - | 3.5–4.5 | - | 0.1 max | 0.4 max |
| Titanium | R55111 | 32 | Titanium Ti-5-1-1-1 | 4.5–5.5 | - | 0.08 max | 0.6–1.2 | - | 0.25 max | - | - | - | 0.06–0.14 | - | - | 0.6–1.4 | balance | - | 0.6–1.4 | - | 0.6–1.4 | - | 0.10 max | - | 0.0125 max | 0.03 max | 0.11 max | - | 0.6–1.4 | - | 0.15 max | 0.4 max |