ASTM F2281 – Mechanical & Material Properties

The ASTM F2281 specification establishes the requirements for stainless steel and nickel alloy fasteners, including bolts, hex cap screws, and studs, specifically designed for heat resistance and high-temperature applications. This standard applies to fasteners with a nominal diameter of 1/4 inch and larger, capable of maintaining structural integrity at temperatures up to 1800°F (982°C). Fasteners under this specification are categorized into three primary "Types" based on their metallurgical structure and intended service environment:

  • Type I: General heat-resisting alloys for continuous service.
    • Class A (Austenitic): Grades 304, 304L, 316, 316L
    • Class B (Martensitic): Grades 410, 416, 431
    • Class C (Ferritic): Grades 430, 430F
  • Type II: Heat-resisting alloys specifically for both continuous and intermittent service applications (Grades 309, 310, 321, 330, 347).
  • Type III: High-temperature alloys for extreme environments.
    • Class A (Nickel-Based): Grades 600, 601
    • Class B & C (Precipitation Hardened): Grades 660 and 718

Mechanical Properties

The reliability of an F2281 fastener depends on its ability to resist creep and oxidation at elevated temperatures. Fasteners must meet specific tensile and yield strengths based on their alloy grade and heat-treated condition.

  • Full-Size Testing: Mandatory for fasteners where the tensile load is 160,000 lb or less. This usually involves a wedge tensile test to simulate real-world bending stresses.
  • Machined Specimen Testing: Permitted for fasteners exceeding 160,000 lb tensile load or those with geometries (like short lengths) that prevent full-size testing.

For Type III Alloys, room-temperature strength is insufficient for safety. When Supplementary Requirement S8 is invoked, fasteners must undergo:

  • Elevated Temperature Tension Tests (E21): To verify minimum strength at the actual service temperature.
  • Creep & Stress-Rupture Tests (E139/E292): To ensure the material will not slowly deform or rupture under constant load over long periods at high heat.

Mechanical Property Requirements
Alloy Grades Condition Marking Nominal Diameter, in. Full-Size Tests Rockwell Hardness Machined Specimen Tests
Tensile Strength, min, ksi Yield Strength, min, ksi Tensile Strength, min, ksi Yield Strength, min, ksi Elongation 4D, min %
Type I, Class A, Heat Resisting Austenitic Grades
304, 304L A F1A All diameters 75 30 65 to 95 HRB 75 30 30
CWA F1B All diameters 75 30 65 to 95 HRB 75 30 30
HWA F1C All diameters 75 30 65 to 95 HRB 75 30 30
316, 316L A F1D All diameters 75 30 65 to 95 HRB 75 30 30
CWA F1E All diameters 75 30 65 to 95 HRB 75 30 30
HWA F1F All diameters 75 30 65 to 95 HRB 75 30 30
Type I, Class B, Heat Resisting Martensitic Grades
410, 416 H F1G Up to 4 diameter 110 85 20 to 30 HRC 110 85 15
HT F1H Up to 4 diameter 160 120 34 to 45 HRC 160 120 12
431 H F1I All diameters 125 100 25 to 32 HRC 125 100 15
HT F1J All diameters 180 140 40 to 48 HRC 180 140 10
Type I, Class C, Heat Resisting Ferritic Grades
430, 430F A F1K All diameters 55 30 65 to 95 HRB 50 25 ...
CWA F1L All diameters 55 30 65 to 95 HRB 50 25 ...
HWA F1M All diameters 55 30 65 to 95 HRB 50 25 ...
Type II, Class A Heat Resisting Austenitic Grades
309, 310 A F2A All diameters 75 30 85 to 95 HRB 75 30 30
CWA F2B All diameters 75 30 65 to 95 HRB 75 30 30
HWA F2C All diameters 75 30 65 to 95 HRB 75 30 30
321, 347 A F2D All diameters 75 30 85 to 95 HRB 75 30 30
CWA F2E All diameters 75 30 65 to 95 HRB 75 30 20
HWA F2F All diameters 75 30 65 to 95 HRB 75 30 30
330 A F2G All diameters 75 30 85 to 95 HRB 75 30 30
CWA F2H All diameters 75 30 65 to 95 HRB 75 30 20
HWA F2I All diameters 75 30 65 to 95 HRB 75 30 30
Type III, Class A, High Temperature, Nickel Alloy Grades
600, 601 A F3A All diameters 80 25 65 to 85 HRB 75 25 35
CWA F3B All diameters 80 25 65 to 85 HRB 75 25 35
HWA F3C All diameters 80 25 65 to 85 HRB 75 25 35
Type III, Class B, High Temperature, Precipitation Hardened Grade
660 AH1 F3D All diameters 130 85 22 to 37 HRC 130 85 15
AH2 F3E All diameters 130 85 22 to 37 HRC 130 85 15
AH3 F3F All diameters 130 85 22 to 37 HRC 130 85 15
Note: Condition AH1 results in increased rupture strength after aging, while Condition AH2 results in better ductility and higher hardness.
Type III, Class C High Temperature, Precipitation Hardened Grade
718 AH4 F3G All diameters 185 150 36 to 48 HRC 180 150 12
Elevated Temperature Mechanical Property Requirements for Type III High Temperature Alloys
Temperature Tensile Strength, min, ksi Yield 0.2 % Strength, min, ksi Elongation in 2 in., min, %
°F °C
Class A—Nickel Based Alloys
Alloy Grade 600 Annealed at 1600°F (871°C)
600 316 89.0 34.0 45.0
1000 538 82.0 33.0 42.0
1400 760 37.0 26.0 70.0
1800 982 11.0 5.0 115.0
Alloy Grade 601 Annealed at 1800°F (982°C)
800 427 104.0 54.5 36.0
1000 538 94.8 51.5 34.0
1200 649 73.5 46.5 32.0
1400 760 37.3 36.6 88.0
1800 982 8.7 7.5 173.0
Class B—Precipitation Hardened Alloys
Alloy Grade 660
800 427 138.0 93.0 18.0
1000 538 131.0 87.5 18.0
1100 593 122.0 90.0 21.0
1200 649 104.0 88.0 13.0
1300 704 86.5 86.0 11.0
1400 760 64.0 62.0 18.0
1500 816 36.5 33.0 68.0
Class C—Precipitation Hardened Alloys
Alloy Grade 718
600 316 184.0 156.0 20.0
1000 538 173.0 148.0 16.0
1200 649 145.0 125.0 12.0
1400 760 124.0 116.0 5.0

Material Properties

All fasteners must conform to the chemical limits of the table below. The manufacturing process—whether the parts are cold-formed, hot-formed, or machined—is at the manufacturer's option unless a specific method is requested by the buyer.

Heat Treatment & Carbide Precipitation

A major technical warning in ASTM F2281 involves the 700°F to 1500°F (371°C to 816°C) range. Prolonged exposure in this window can cause chromium carbide precipitation, which reduces corrosion resistance and impact strength. To mitigate this, the standard provides specific heat treatment instructions to ensure carbides remain in solution or the material is properly stabilized.

The following heat treatment protocols are mandated based on the alloy type and required condition:

  • Austenitic Alloys (Types I Class A & II): These must be heated between 1850°F and 1950°F (1010°C to 1066°C) and cooled rapidly to prevent carbide precipitation.
  • Ferritic Alloys (Type I Class C): These require heating to 1400°F to 1500°F (760°C to 816°C) followed by air cooling.
  • Martensitic Alloys (Type I Class B): Conditions H and HT involve hardening by heating to 1800°F to 1900°F (982°C to 1038°C), quenching, and then tempering at a minimum of 1050°F (565°C) or 525°F (274°C) respectively.
  • Nickel-Based Alloys (Type III Class A): Condition A requires heating to 1600°F to 1800°F (871°C to 982°C), holding for 10 to 15 minutes, and water quenching or air cooling.
  • Precipitation Hardened Alloys (Type III Classes B & C): These involve complex multi-stage aging cycles. For example, Condition AH4 (Grade 718) requires solution treatment at 1725°F to 1850°F, followed by a specific two-stage aging process starting at 1325°F and finishing at 1150°F to reach a total heat treat time of 18 hours.

Chemical Requirements
Composition, % maximum except as shown
Alloy Carbon Manganese Phosphorus Sulfur Silicon Chromium Nickel Copper Molybdenum Other
Type I, Class A, Heat Resisting Austenitic Grades
304 0.08 2.00 0.045 0.030 1.00 18.0/20.0 8.0/10.5 1.00
304L 0.03 2.00 0.045 0.030 1.00 18.0/20.0 8.0/12.0 1.00
316 0.08 2.00 0.045 0.030 1.00 16.0/18.0 10.0/14.0 2.00/3.00
316L 0.03 2.00 0.045 0.030 1.00 16.0/18.0 10.0/14.0 2.00/3.00
Type I, Class B, Heat Resisting Martensitic Grades
410 0.15 1.00 0.040 0.030 1.00 11.5/13.5
416 0.15 1.25 0.060 0.15 min 1.00 12.0/14.0 0.60
431 0.20 1.00 0.040 0.030 1.00 15.0/17.0 1.25/2.50
Type I, Class C, Heat Resisting Ferritic Grades
430 0.12 1.00 0.040 0.030 1.00 16.0/18.0
430F 0.12 1.25 0.060 0.15 min 1.00 16.0/18.0 0.60
Type II, Heat Resisting Austenitic Grades
309 0.20 2.00 0.045 0.030 1.00 22.0/24.0 12.0/15.0
310 0.25 2.00 0.045 0.030 1.50 24.0/26.0 19.0/22.0
321 0.08 2.00 0.045 0.030 1.00 17.0/19.0 9.0/12.0 Ti 5 × C min
330 0.08 2.00 0.030 0.030 0.75/1.50 17.0/20.0 34.0/37.0
347 0.08 2.00 0.045 0.030 1.00 17.0/19.0 9.0/13.0 Cb + Ta 10 × C min
Type III, Class A, High Temperature, Nickel Alloy Grades
600 0.10 1.00 0.015 0.50 14.0/17.0 72.0 min 0.50 Fe 6.0/10.0
601 0.10 1.00 0.015 0.50 21.0/25.0 58.0/63.0 1.00 Al 1.0/1.7; Fe remainder
Type III, Class B, High Temperature, Precipitation Hardened Grade
660 0.08 2.00 0.040 0.030 1.00 13.5/16.0 24.0/27.0 1.00/1.75 Ti 1.90/2.30; V 0.10/0.50; Al 0.35 max; B 0.003/0.010; Fe remainder
Type III, Class C, High Temperature, Precipitation Hardened Grade
718 0.08 0.35 0.015 0.015 0.35 17.0/21.0 50.0/55.0 0.30 2.80/3.30 Ti 0.65/1.15; Co 1.00 max; Al 0.20/0.80; B 0.006 max; Cb + Ta 4.75/5.50; Fe remainder