ASTM F2281 – Mechanical & Material Properties
The ASTM F2281 specification establishes the requirements for stainless steel and nickel alloy fasteners, including bolts, hex cap screws, and studs, specifically designed for heat resistance and high-temperature applications. This standard applies to fasteners with a nominal diameter of 1/4 inch and larger, capable of maintaining structural integrity at temperatures up to 1800°F (982°C). Fasteners under this specification are categorized into three primary "Types" based on their metallurgical structure and intended service environment:
-
Type I: General heat-resisting alloys for continuous service.
- Class A (Austenitic): Grades 304, 304L, 316, 316L
- Class B (Martensitic): Grades 410, 416, 431
- Class C (Ferritic): Grades 430, 430F
- Type II: Heat-resisting alloys specifically for both continuous and intermittent service applications (Grades 309, 310, 321, 330, 347).
-
Type III: High-temperature alloys for extreme environments.
- Class A (Nickel-Based): Grades 600, 601
- Class B & C (Precipitation Hardened): Grades 660 and 718
Mechanical Properties
The reliability of an F2281 fastener depends on its ability to resist creep and oxidation at elevated temperatures. Fasteners must meet specific tensile and yield strengths based on their alloy grade and heat-treated condition.
- Full-Size Testing: Mandatory for fasteners where the tensile load is 160,000 lb or less. This usually involves a wedge tensile test to simulate real-world bending stresses.
- Machined Specimen Testing: Permitted for fasteners exceeding 160,000 lb tensile load or those with geometries (like short lengths) that prevent full-size testing.
For Type III Alloys, room-temperature strength is insufficient for safety. When Supplementary Requirement S8 is invoked, fasteners must undergo:
- Elevated Temperature Tension Tests (E21): To verify minimum strength at the actual service temperature.
- Creep & Stress-Rupture Tests (E139/E292): To ensure the material will not slowly deform or rupture under constant load over long periods at high heat.
| Mechanical Property Requirements | |||||||||
|---|---|---|---|---|---|---|---|---|---|
| Alloy Grades | Condition | Marking | Nominal Diameter, in. | Full-Size Tests | Rockwell Hardness | Machined Specimen Tests | |||
| Tensile Strength, min, ksi | Yield Strength, min, ksi | Tensile Strength, min, ksi | Yield Strength, min, ksi | Elongation 4D, min % | |||||
| Type I, Class A, Heat Resisting Austenitic Grades | |||||||||
| 304, 304L | A | F1A | All diameters | 75 | 30 | 65 to 95 HRB | 75 | 30 | 30 |
| CWA | F1B | All diameters | 75 | 30 | 65 to 95 HRB | 75 | 30 | 30 | |
| HWA | F1C | All diameters | 75 | 30 | 65 to 95 HRB | 75 | 30 | 30 | |
| 316, 316L | A | F1D | All diameters | 75 | 30 | 65 to 95 HRB | 75 | 30 | 30 |
| CWA | F1E | All diameters | 75 | 30 | 65 to 95 HRB | 75 | 30 | 30 | |
| HWA | F1F | All diameters | 75 | 30 | 65 to 95 HRB | 75 | 30 | 30 | |
| Type I, Class B, Heat Resisting Martensitic Grades | |||||||||
| 410, 416 | H | F1G | Up to 4 diameter | 110 | 85 | 20 to 30 HRC | 110 | 85 | 15 |
| HT | F1H | Up to 4 diameter | 160 | 120 | 34 to 45 HRC | 160 | 120 | 12 | |
| 431 | H | F1I | All diameters | 125 | 100 | 25 to 32 HRC | 125 | 100 | 15 |
| HT | F1J | All diameters | 180 | 140 | 40 to 48 HRC | 180 | 140 | 10 | |
| Type I, Class C, Heat Resisting Ferritic Grades | |||||||||
| 430, 430F | A | F1K | All diameters | 55 | 30 | 65 to 95 HRB | 50 | 25 | ... |
| CWA | F1L | All diameters | 55 | 30 | 65 to 95 HRB | 50 | 25 | ... | |
| HWA | F1M | All diameters | 55 | 30 | 65 to 95 HRB | 50 | 25 | ... | |
| Type II, Class A Heat Resisting Austenitic Grades | |||||||||
| 309, 310 | A | F2A | All diameters | 75 | 30 | 85 to 95 HRB | 75 | 30 | 30 |
| CWA | F2B | All diameters | 75 | 30 | 65 to 95 HRB | 75 | 30 | 30 | |
| HWA | F2C | All diameters | 75 | 30 | 65 to 95 HRB | 75 | 30 | 30 | |
| 321, 347 | A | F2D | All diameters | 75 | 30 | 85 to 95 HRB | 75 | 30 | 30 |
| CWA | F2E | All diameters | 75 | 30 | 65 to 95 HRB | 75 | 30 | 20 | |
| HWA | F2F | All diameters | 75 | 30 | 65 to 95 HRB | 75 | 30 | 30 | |
| 330 | A | F2G | All diameters | 75 | 30 | 85 to 95 HRB | 75 | 30 | 30 |
| CWA | F2H | All diameters | 75 | 30 | 65 to 95 HRB | 75 | 30 | 20 | |
| HWA | F2I | All diameters | 75 | 30 | 65 to 95 HRB | 75 | 30 | 30 | |
| Type III, Class A, High Temperature, Nickel Alloy Grades | |||||||||
| 600, 601 | A | F3A | All diameters | 80 | 25 | 65 to 85 HRB | 75 | 25 | 35 |
| CWA | F3B | All diameters | 80 | 25 | 65 to 85 HRB | 75 | 25 | 35 | |
| HWA | F3C | All diameters | 80 | 25 | 65 to 85 HRB | 75 | 25 | 35 | |
| Type III, Class B, High Temperature, Precipitation Hardened Grade | |||||||||
| 660 | AH1 | F3D | All diameters | 130 | 85 | 22 to 37 HRC | 130 | 85 | 15 |
| AH2 | F3E | All diameters | 130 | 85 | 22 to 37 HRC | 130 | 85 | 15 | |
| AH3 | F3F | All diameters | 130 | 85 | 22 to 37 HRC | 130 | 85 | 15 | |
| Note: Condition AH1 results in increased rupture strength after aging, while Condition AH2 results in better ductility and higher hardness. | |||||||||
| Type III, Class C High Temperature, Precipitation Hardened Grade | |||||||||
| 718 | AH4 | F3G | All diameters | 185 | 150 | 36 to 48 HRC | 180 | 150 | 12 |
| Elevated Temperature Mechanical Property Requirements for Type III High Temperature Alloys | |||||
|---|---|---|---|---|---|
| Temperature | Tensile Strength, min, ksi | Yield 0.2 % Strength, min, ksi | Elongation in 2 in., min, % | ||
| °F | °C | ||||
| Class A—Nickel Based Alloys Alloy Grade 600 Annealed at 1600°F (871°C) |
|||||
| 600 | 316 | 89.0 | 34.0 | 45.0 | |
| 1000 | 538 | 82.0 | 33.0 | 42.0 | |
| 1400 | 760 | 37.0 | 26.0 | 70.0 | |
| 1800 | 982 | 11.0 | 5.0 | 115.0 | |
| Alloy Grade 601 Annealed at 1800°F (982°C) | |||||
| 800 | 427 | 104.0 | 54.5 | 36.0 | |
| 1000 | 538 | 94.8 | 51.5 | 34.0 | |
| 1200 | 649 | 73.5 | 46.5 | 32.0 | |
| 1400 | 760 | 37.3 | 36.6 | 88.0 | |
| 1800 | 982 | 8.7 | 7.5 | 173.0 | |
| Class B—Precipitation Hardened Alloys Alloy Grade 660 |
|||||
| 800 | 427 | 138.0 | 93.0 | 18.0 | |
| 1000 | 538 | 131.0 | 87.5 | 18.0 | |
| 1100 | 593 | 122.0 | 90.0 | 21.0 | |
| 1200 | 649 | 104.0 | 88.0 | 13.0 | |
| 1300 | 704 | 86.5 | 86.0 | 11.0 | |
| 1400 | 760 | 64.0 | 62.0 | 18.0 | |
| 1500 | 816 | 36.5 | 33.0 | 68.0 | |
| Class C—Precipitation Hardened Alloys Alloy Grade 718 |
|||||
| 600 | 316 | 184.0 | 156.0 | 20.0 | |
| 1000 | 538 | 173.0 | 148.0 | 16.0 | |
| 1200 | 649 | 145.0 | 125.0 | 12.0 | |
| 1400 | 760 | 124.0 | 116.0 | 5.0 | |
Material Properties
All fasteners must conform to the chemical limits of the table below. The manufacturing process—whether the parts are cold-formed, hot-formed, or machined—is at the manufacturer's option unless a specific method is requested by the buyer.
Heat Treatment & Carbide Precipitation
A major technical warning in ASTM F2281 involves the 700°F to 1500°F (371°C to 816°C) range. Prolonged exposure in this window can cause chromium carbide precipitation, which reduces corrosion resistance and impact strength. To mitigate this, the standard provides specific heat treatment instructions to ensure carbides remain in solution or the material is properly stabilized.
The following heat treatment protocols are mandated based on the alloy type and required condition:
- Austenitic Alloys (Types I Class A & II): These must be heated between 1850°F and 1950°F (1010°C to 1066°C) and cooled rapidly to prevent carbide precipitation.
- Ferritic Alloys (Type I Class C): These require heating to 1400°F to 1500°F (760°C to 816°C) followed by air cooling.
- Martensitic Alloys (Type I Class B): Conditions H and HT involve hardening by heating to 1800°F to 1900°F (982°C to 1038°C), quenching, and then tempering at a minimum of 1050°F (565°C) or 525°F (274°C) respectively.
- Nickel-Based Alloys (Type III Class A): Condition A requires heating to 1600°F to 1800°F (871°C to 982°C), holding for 10 to 15 minutes, and water quenching or air cooling.
- Precipitation Hardened Alloys (Type III Classes B & C): These involve complex multi-stage aging cycles. For example, Condition AH4 (Grade 718) requires solution treatment at 1725°F to 1850°F, followed by a specific two-stage aging process starting at 1325°F and finishing at 1150°F to reach a total heat treat time of 18 hours.
| Chemical Requirements | ||||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Composition, % maximum except as shown | ||||||||||
| Alloy | Carbon | Manganese | Phosphorus | Sulfur | Silicon | Chromium | Nickel | Copper | Molybdenum | Other |
| Type I, Class A, Heat Resisting Austenitic Grades | ||||||||||
| 304 | 0.08 | 2.00 | 0.045 | 0.030 | 1.00 | 18.0/20.0 | 8.0/10.5 | 1.00 | ||
| 304L | 0.03 | 2.00 | 0.045 | 0.030 | 1.00 | 18.0/20.0 | 8.0/12.0 | 1.00 | ||
| 316 | 0.08 | 2.00 | 0.045 | 0.030 | 1.00 | 16.0/18.0 | 10.0/14.0 | 2.00/3.00 | ||
| 316L | 0.03 | 2.00 | 0.045 | 0.030 | 1.00 | 16.0/18.0 | 10.0/14.0 | 2.00/3.00 | ||
| Type I, Class B, Heat Resisting Martensitic Grades | ||||||||||
| 410 | 0.15 | 1.00 | 0.040 | 0.030 | 1.00 | 11.5/13.5 | ||||
| 416 | 0.15 | 1.25 | 0.060 | 0.15 min | 1.00 | 12.0/14.0 | 0.60 | |||
| 431 | 0.20 | 1.00 | 0.040 | 0.030 | 1.00 | 15.0/17.0 | 1.25/2.50 | |||
| Type I, Class C, Heat Resisting Ferritic Grades | ||||||||||
| 430 | 0.12 | 1.00 | 0.040 | 0.030 | 1.00 | 16.0/18.0 | ||||
| 430F | 0.12 | 1.25 | 0.060 | 0.15 min | 1.00 | 16.0/18.0 | 0.60 | |||
| Type II, Heat Resisting Austenitic Grades | ||||||||||
| 309 | 0.20 | 2.00 | 0.045 | 0.030 | 1.00 | 22.0/24.0 | 12.0/15.0 | |||
| 310 | 0.25 | 2.00 | 0.045 | 0.030 | 1.50 | 24.0/26.0 | 19.0/22.0 | |||
| 321 | 0.08 | 2.00 | 0.045 | 0.030 | 1.00 | 17.0/19.0 | 9.0/12.0 | Ti 5 × C min | ||
| 330 | 0.08 | 2.00 | 0.030 | 0.030 | 0.75/1.50 | 17.0/20.0 | 34.0/37.0 | |||
| 347 | 0.08 | 2.00 | 0.045 | 0.030 | 1.00 | 17.0/19.0 | 9.0/13.0 | Cb + Ta 10 × C min | ||
| Type III, Class A, High Temperature, Nickel Alloy Grades | ||||||||||
| 600 | 0.10 | 1.00 | 0.015 | 0.50 | 14.0/17.0 | 72.0 min | 0.50 | Fe 6.0/10.0 | ||
| 601 | 0.10 | 1.00 | 0.015 | 0.50 | 21.0/25.0 | 58.0/63.0 | 1.00 | Al 1.0/1.7; Fe remainder | ||
| Type III, Class B, High Temperature, Precipitation Hardened Grade | ||||||||||
| 660 | 0.08 | 2.00 | 0.040 | 0.030 | 1.00 | 13.5/16.0 | 24.0/27.0 | 1.00/1.75 | Ti 1.90/2.30; V 0.10/0.50; Al 0.35 max; B 0.003/0.010; Fe remainder | |
| Type III, Class C, High Temperature, Precipitation Hardened Grade | ||||||||||
| 718 | 0.08 | 0.35 | 0.015 | 0.015 | 0.35 | 17.0/21.0 | 50.0/55.0 | 0.30 | 2.80/3.30 | Ti 0.65/1.15; Co 1.00 max; Al 0.20/0.80; B 0.006 max; Cb + Ta 4.75/5.50; Fe remainder |