ASTM F468 – Mechanical & Material Property

The ASTM F468 specification establishes the chemical, mechanical, and dimensional requirements for commercial wrought nonferrous fasteners intended for general service applications. This standard is a critical reference for engineers and procurement professionals selecting fasteners that require specific properties like corrosion resistance, high strength-to-weight ratios, or non-magnetic characteristics. This specification covers three primary fastener types: bolts, hex cap screws, and studs with nominal diameters ranging from 0.250 to 1.500 in. inclusive. It categorizes materials into four major alloy groups:

  • Copper and Copper-Base Alloys: Including ETP copper (110), various brasses, naval brass, and silicon/aluminum bronzes.
  • Nickel and Nickel-Base Alloys: Including Ni-Cu (400/405), Ni-Cu-Al (500), and high-performance Ni-Cr-Mo alloys like 625 and 276.
  • Aluminum-Base Alloys: Specifically 2024-T4, 6061-T6, and 7075-T73 tempers.
  • Titanium and Titanium-Base Alloys: Ranging from commercially pure Grades 1, 2, and 4 to high-strength alloys like Ti-6Al-4V (Grade 5).

For complementary components, nuts used with these fasteners are covered under the ASTM F467 specification. To correctly apply this specification to your project or procurement, the following technical requirements must be observed:

Fasteners may be cold formed, hot formed, or machined at the manufacturer's option unless a specific process is requested. The final condition is alloy-dependent:

  • Copper and Nickel 400/405: Typically furnished as formed or stress relieved at the manufacturer's option.
  • Nickel 500: Must be solution annealed and aged.
  • Aluminum Alloys: Must be solution treated and aged (naturally, artificially, or stabilized depending on the alloy).

Mechanical Properties

The mechanical property requirements for fasteners under the ASTM F468 specification are determined by the specific alloy, the length of the product, and its nominal diameter. These properties are essential for ensuring that nonferrous bolts, screws, and studs can withstand the intended service loads without failure.

To verify compliance, the specification defines two primary testing methods: Full-Size Testing is preferred for fasteners with a breaking load of 120,000 lbf or less to measure actual tensile and yield strength, while Machined Specimen Testing is used for fasteners exceeding that load or where full-size testing is impractical. In any instance where both tension and hardness tests are conducted, the tension test results take precedence for final Acceptance Priority.

The mechanical integrity of these fasteners is governed by several critical factors: Yield Strength Calculation for full-size products uses the specific Tensile Stress Area (As) for the product diameter and thread pitch, with the yield point defined at an offset of 0.2% gage length. Ductility is measured as "Elongation in 4D," using a gage length equivalent to four times the diameter of the test specimen.

For alloys other than aluminum and titanium, fasteners too short for tension testing must conform to specific Hardness Requirements. For aluminum alloys, when tension testing is not feasible, a shear test must be performed, requiring minimum strengths such as 37 ksi for 2024-T4 or 41 ksi for 7075-T73.

Mechanical Properties Requirements
Alloy Mechanical Property Marking Nominal Thread Diameter, in. Full-Size Tests Machined Specimen Tests
Tensile Strength, min, ksi Yield Strength, min, ksi Tensile Strength, min, ksi Yield Strength, min, ksi Elongation in 4D, min, %
Copper and Copper-Base Alloys
Cu 110F 468Aall3010301015
Cu 260F 468ABall5550555035
Cu 270F 468Ball5550555035
Cu 462F 468Call5025502520
Cu 464F 468Dall5015501525
Cu 510F 468Eall6035553015
Cu 613F 468F1/4 to 1/28050805030
Cu 613F 468F5/8 to 1-1/27545754530
Cu 614F 468Gall7535753530
Cu 630F 468Hall10050100505
Cu 642F 468Jall7535753510
Cu 651F 468K1/4 to 3/4705570538
Cu 651F 468K7/8 to 1-1/2544054388
Cu 655F 468Lall5020501520
Cu 661F 468Mall7035703515
Cu 675F 468Nall5525552520
Cu 710F 468Pall4515451540
Cu 715F 468Rall5520552045
Nickel and Nickel-Base Alloys
Ni 59 Grade 1F468FNall120851208520
Ni 59 Grade 2F468GNall13512513512520
Ni 59 Grade 3F468HNall16015016015020
Ni 59 Grade 4F468JNall100451004525
Ni 335F 468Sall115451154535
Ni 276F 468Tall110451104525
Ni 400F 468U1/4 to 3/48040804020
Ni 400F 468U7/8 to 1-1/27030703020
Ni 400 HFF 468HFall7030703020
Ni 405F 468Vall7030703020
Ni 500F 468W1/4 to 7/8130901309020
Ni 500F 468W1 to 1-1/2130851308520
Ni 625F 468ACall120601206030
Ni 686 Grade 1F468BNall120851208520
Ni 686 Grade 2F468CNall13512513512520
Ni 686 Grade 3F468DNall16015016015020
Ni 686 Grade 4F468ENall100451004525
Aluminum-Base Alloys
Al 2024-T4F 468Xall6236624010
Al 6061-T6F 468Yall4231423510
Al 7075-T73F 468Zall6850685610
Titanium and Titanium-Base Alloys
Ti 1F 468ATall3530352524
Ti 2F 468BTall5045504020
Ti 4F 468CTall8075807015
Ti 5 Class AF 468DTall13012513012010
Ti 5 Class BF 468HTall13012513012010
Ti 7F 468ETall5045504020
Ti 19F 468FTall12011512011515
Ti 23F 468GTall12011012011010
Ti-5-1-1-1F 468HTall100901008510
Tensile Stress Areas and Threads per Inch
Nominal Size, in. Coarse Threads—UNC Fine Threads—UNF 8 Thread Series—8UN
Threads/in. Stress Area, in.² Threads/in. Stress Area, in.² Threads/in. Stress Area, in.²
1/4 20 0.0318 28 0.0364
5/16 18 0.0524 24 0.0580
3/8 16 0.0775 24 0.0878
7/16 14 0.1063 20 0.1187
1/2 13 0.1419 20 0.1599
9/16 12 0.1820 18 0.2030
5/8 11 0.2260 18 0.2560
3/4 10 0.3340 16 0.3730
7/8 9 0.4620 14 0.5090
1 8 0.6060 12 0.6630
1-1/8 7 0.7630 12 0.8560 8 0.790
1-1/4 7 0.9690 12 1.0730 8 1.000
1-3/8 6 1.1550 12 1.3150 8 1.233
1-1/2 6 1.4050 12 1.5810 8 1.492

Material Properties

The material and chemical properties of fasteners under the ASTM F468 specification are strictly defined to ensure consistency and performance across a wide range of nonferrous alloys. These requirements govern the elemental makeup of the finished products, providing the foundation for their unique mechanical and corrosion-resistant characteristics.

To maintain high quality standards, the specification mandates several layers of chemical verification:

  • Strict Elemental Limits: Fasteners must conform to the specific chemical requirements detailed in Table 1 for their designated alloy.
  • Balance Elements: For many alloys, the primary element (e.g., Copper, Aluminum, or Titanium) is calculated arithmetically as the "balance" by subtracting the total of all other named elements from 100%.
  • Verification Methods: Manufacturers may perform analysis on randomly selected finished fasteners or report the analysis of the raw material, provided that heat and lot identities have been strictly maintained.
  • Residual Elements: Elements present in small quantities inherent to the manufacturing process but not intentionally added are considered residuals. These typically do not need to be reported unless explicitly required by the purchaser.

Different alloy groups have specific requirements that must be followed for full compliance:

  • Nickel Alloys: For all nickel-base alloys, cobalt is to be counted as nickel. Additionally, Alloy 625 material must be refined using either electroslag remelting (ESR) or vacuum arc remelting (VAR) processes.
  • Aluminum Alloys: For aluminum fasteners, manufacturers have the option to furnish a certificate of conformance instead of detailed test reports to certify compliance with the chemical composition.
  • Copper Alloys: Certain silicon bronze alloys, such as C65100, have specific provisions where an alloy containing up to 2.6% silicon is acceptable under certain elemental sum conditions.
Chemical Composition, (%)
Group UNS Designation Number Alloy Number General Name Aluminum Arsenic Carbon Chromium Copper Iron Manganese Nickel Phosphorus Silicon Zinc Lead Tin Titanium Cobalt Molybdenum Sulfur Vanadium Tungsten Niobium Magnesium Hydrogen Nitrogen Oxygen Palladium Zirconium Ruthenium Residuals (Each) Residuals (Total)
Copper and Copper-Base Alloys
CopperC11000110ETP copper----99.9 min------------------------
CopperC26000260brass----68.5–71.50.05 max----balance0.07 max-----------------
CopperC27000270brass----63.0–68.50.07 max----balance0.10 max-----------------
CopperC46200462naval brass----62.0–65.00.10 max----balance0.20 max0.5–1.0----------------
CopperC46400464naval brass----59.0–62.00.10 max----balance0.20 max0.5–1.0----------------
CopperC51000510phosphor bronze----balance0.10 max--0.03–0.35-0.30 max0.05 max4.2–5.8----------------
CopperC61300613aluminum bronze6.0–7.5---balance2.0–3.00.10 max0.10 max0.015 max0.10 max0.05 max0.01 max0.20–0.50----------------
CopperC61400614aluminum bronze6.0–8.0---88.00 min1.5–3.51.0 max----------------------
CopperC63000630aluminum bronze9.0–11.0---78.00 min2.0–4.01.5 max4.0–5.5-0.25 max--0.20 max----------------
CopperC64200642aluminum silicon bronze6.3–7.60.15 max--88.65 min0.30 max0.10 max0.25 max-1.5–2.250.50 max0.05 max0.20 max----------------
CopperC65100651silicon bronze----96.00 min0.8 max0.7 max--0.8–2.01.5 max0.05 max-----------------
CopperC65500655silicon bronze----94.80 min0.8 max1.5 max0.6 max-2.8–3.81.5 max0.05 max-----------------
CopperC66100661silicon bronze----94.00 min0.25 max1.5 max--2.8–3.51.5 max0.20–0.8-----------------
CopperC67500675manganese bronze----57.0–60.00.8–2.00.05–0.5---balance0.20 max0.5–1.5----------------
CopperC71000710cupro-nickel----74.00 min0.60 max1.00 max19.0–23.00--1.00 max0.05 max-----------------
CopperC71500715cupro-nickel----65.00 min0.40–0.71.00 max29.0–33.0--1.00 max0.05 max-----------------
Nickel and Nickel-Base Alloys
NickelN10001335NiMo2.30–3.15-0.05 max1.0 max-4.0–6.01.0 maxbalance-1.00 max----2.50 max26.0–30.00.030 max0.2–0.4-----------
NickelN10276276Ni-Mo-Cr--0.02 max14.5–16.5-4.0–7.01.00 maxbalance0.040 max0.08 max----2.50 max15.0–17.00.030 max0.35 max3.0–4.5----------
NickelN04400400NiCu -Class A--0.3 max-balance2.5 max2.0 max63.0–70.0-0.5 max------0.024 max------------
NickelN04405405Ni-Cu Class B--0.3 max-balance2.5 max2.0 max63.0–70.0-0.5 max------0.025–0.060------------
NickelN05500500NiCu-Al2.30–3.15-0.25 max-balance2.0 max1.5 max63.0–70.0-0.5 max---0.35–0.85--0.010 max------------
NickelN0605959NiCr-Mo0.1–0.4-0.010 max22.0–24.00.5 max1.5 max0.5 maxbalance0.015 max0.10 max-----15.0–16.50.010 max------------
NickelN06625625Ni-Cr-Mo-Cb0.40 max-0.10 max20.0–23.0-5.0 max0.50 max58.0 min0.015 max0.50 max---0.40 max1.00 max8.0–10.00.015 max--3.15–4.15---------
NickelN06686686NiCr--MoW---0.010 max19.0–23.00-5.0 max0.75 maxbalance0.04 max0.08 max---0.02–0.25-15.0–17.00.02 max-3.0–4.4----------
Aluminum-Base Alloys
AluminumA920242024Aluminum 2024balance--0.10 max3.8–4.90.50 max0.30–0.9--0.50 max0.25 max--0.15 max------1.2–1.8------0.05 max0.15 max
AluminumA960616061Aluminum 6061balance--0.04–0.350.15–0.400.7 max0.15 max--0.40–0.80.25 max--0.15 max------0.8–1.2------0.05 max0.15 max
AluminumA970757075Aluminum 7075balance--0.18–0.351.2–2.00.50 max0.30 max--0.40 max5.1–6.1--0.200 max------2.1–2.9------0.05 max0.15 max
Titanium and Titanium-Base Alloys
TitaniumR502501Titanium Gr 1--0.10 max--0.20 max-------balance-------0.0125 max0.05 max0.18 max---0.1 max0.4 max
TitaniumR504002Titanium Gr 2--0.10 max--0.30 max-------balance-------0.0125 max0.05 max0.25 max---0.1 max0.4 max
TitaniumR507004Titanium Gr 4--0.10 max--0.50 max-------balance-------0.0125 max0.07 max0.40 max---0.1 max0.4 max
TitaniumR564005Titanium Gr 55.5–6.75-0.10 max--0.40 max-------balance---3.5–4.5---0.0125 max0.05 max0.20 max---0.1 max0.4 max
TitaniumR5640123Titanium Ti-6Al-4V ELI5.5–6.5-0.08 max--0.25 max-------balance---3.5–4.5---0.0125 max0.05 max0.13 max---0.1 max0.4 max
TitaniumR524007Titanium Gr 7--0.10 max--0.30 max-------balance-------0.0125 max0.05 max0.25 max0.12–0.25--0.1 max0.4 max
TitaniumR5864019Titanium Ti-38-6-443.0–4.0-0.05 max5.5–6.5-0.30 max---0.10 max---balance-3.5–4.5-7.5–8.5---0.0200 max0.03 max0.12 max-3.5–4.5-0.1 max0.4 max
TitaniumR5511132Titanium Ti-5-1-1-14.5–5.5-0.08 max0.6–1.2-0.25 max---0.06–0.14--0.6–1.4balance-0.6–1.4-0.6–1.4-0.10 max-0.0125 max0.03 max0.11 max-0.6–1.4-0.15 max0.4 max